The relative reactivity of photosolvolysis of a number of substituted benzyl acetates is in the order ortho > meta > para, these substitutent effects being apparently additive, as suggested by the relative reactivity of photomethanolysis of several dimethoxy-substituted benzyl alcohols. The photoso
Structure?reactivity studies and catalytic effects in the photosolvolysis of methoxy-substituted benzyl alcohols
β Scribed by Wan, Peter; Chak, Becky
- Book ID
- 120552946
- Publisher
- Royal Society of Chemistry
- Year
- 1986
- Tongue
- English
- Weight
- 997 KB
- Volume
- 11
- Category
- Article
- ISSN
- 1472-779X
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## Abstract DFT computations on the mechanisms of nucleophilic substitutions on benzyl bromides were performed and the calculated activation parameters were compared with experimentally acquired data. In vacuo, the presence of electronβwithdrawing (eβw) groups on the benzyl bromides accelerated the
BBCP was prepared by the reported method . The preparation, purification, and specification of the substituted benzyl alcohols and β£,β£-dideuteriobenzyl alcohol (PhCD 2 OH) have been described earlier . Acetic acid was refluxed with chromic oxide and acetic anhydride for 6 h and then fractionated. Pe