Comparative Study of the Reactivities of Substituted 3-(Benzoyl)benzyl Carbanions in Water and in DMSO
✍ Scribed by Llauger, Laura; Miranda, Miguel A.; Cosa, Gonzalo; Scaiano, J. C.
- Book ID
- 121880175
- Publisher
- American Chemical Society
- Year
- 2004
- Tongue
- English
- Weight
- 109 KB
- Volume
- 69
- Category
- Article
- ISSN
- 0022-3263
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📜 SIMILAR VOLUMES
## Abstract DFT computations on the mechanisms of nucleophilic substitutions on benzyl bromides were performed and the calculated activation parameters were compared with experimentally acquired data. In vacuo, the presence of electron‐withdrawing (e‐w) groups on the benzyl bromides accelerated the
## Abstract The rate constants of peroxy radical recombination in the oxidation of 1‐methyl‐3‐phenylindan, 1,3‐dimethyl‐3‐phenylindan, and 1,1‐dimethyl‐3‐phenylindan were measured using the nonstationary‐state technique. A cooxidation method was applied to obtain the reactivities of these compounds