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Structure-reactivity relationships in the aminolysis of O-ethyl S-aryl dithiocarbonates in aqueous solution

✍ Scribed by Castro, Enrique A.; Cubillos, Maria; Ibanez, Fernando; Moraga, Inge; Santos, Jose G.

Book ID
126486567
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
590 KB
Volume
58
Category
Article
ISSN
0022-3263

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The reactions of the title substrate with a series of secondary alicyclic amines are subjected to a kinetic study in 44 wt% aqueous ethanol, 25.0°C, and ionic strength 0.2 M (KC1). The Bronsted-type plot (log k~ vs. pKa of the amine, where k~ is the second-order rate coefficient) obtained is linear