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Structure−Reactivity Correlations in the Aminolysis of Ethyl S -Aryl Thiolcarbonates

✍ Scribed by Castro, Enrique A.; Cubillos, María; Santos, José G.

Book ID
127075244
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
59 KB
Volume
64
Category
Article
ISSN
0022-3263

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Structure–reactivity correlations in the
Structure–reactivity correlations in the aminolysis of aryl chloroformates
✍ Enrique A. Castro; María G. Ruiz; José G. Santos 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 137 KB

The reactions of a series of secondary alicyclic amines with 4-methylphenyl and 4-methoxyphenyl chloroformates are subjected to a kinetic investigation in water, at 25.0ЊC, ionic strength 0.2 M (KCl). Under amine excess, pseudo-first-order rate coefficients (k obs ) are found for all reactions. Plot