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Structure-reactivity correlations in the reaction of ethyl bromoacetate with aliphatic carboxylate ions

✍ Scribed by A. Shunmugasundram; T. Bupathi Ganesh

Book ID
112906842
Publisher
Indian Academy of Sciences,Royal Society of Chemistry
Year
1989
Tongue
English
Weight
259 KB
Volume
101
Category
Article
ISSN
0253-4134

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ethyl S- (2,4,6-trinitrophenyl) dithiocarbonate [1] and a stepwise path through a tetrahedral intermediate in the other reactions [2,3]. In the reaction of O-ethyl Sphenyl dithiocarbonate the zwitterionic tetrahedral intermediate formed by the amine attack can be deprotonated to yield an anionic int