𝔖 Bobbio Scriptorium
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Structure of trichodiene

✍ Scribed by Shigeo Nozoe; Yoshimasa Machida


Book ID
104249118
Publisher
Elsevier Science
Year
1970
Tongue
French
Weight
183 KB
Volume
11
Category
Article
ISSN
0040-4039

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πŸ“œ SIMILAR VOLUMES


A diastereoselective synthesis of (Β±) tr
✍ John C. Gilbert; Terence A. Kelly πŸ“‚ Article πŸ“… 1989 πŸ› Elsevier Science 🌐 French βš– 254 KB

A route to the total synthesis of the title compound is described. The key step involves the [3,3] sigmatropic of the silyl keteneacetal derived from an allylic P-ketoester. The potential application of this protocol to the construction of the higher trichothecenes is also discussed.

Structures of new metabolites from Fusar
✍ Lolita O. Zamir; Kenneth A. Devor; Anastasia Nikolakakis; Yves Nadeau; FranΓ§oise πŸ“‚ Article πŸ“… 1992 πŸ› Elsevier Science 🌐 French βš– 312 KB

Three new natural products were isolated from Fumrium spp, one apotricho~ aad two oxygenated derivatives of trichodiene. The apotrichothecene was a precu&r to apotrichcdiol and saa~buci-IIOI. Apotrichothecenes were for a long time considered to be the products of the trichothecenes under acidic con

Synthesis of [16-14C]trichodiene the pre
✍ Lolita O. Zamir; Liren Huang πŸ“‚ Article πŸ“… 1992 πŸ› John Wiley and Sons 🌐 French βš– 387 KB

## Abstract The synthesis of radiolabelled trichodiene with ^14^C at the olefinic methyl (C‐16) is described. The isotope was introduced using a ^14^C‐Wittig reagent prepared __in situ__ from triphenyl phosphine and ^14^C‐methyliodide.