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Structure of the copper(II) complex of 2-acetylpyridine hexamethyleneiminylthiosemicarbazone, [Cu(Lhexim)Br]

✍ Scribed by Ray J. Butcher; Douglas X. West

Publisher
Springer
Year
1993
Tongue
English
Weight
327 KB
Volume
18
Category
Article
ISSN
0340-4285

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✦ Synopsis

An anion (loss of 3N hydrogen) of a 2-acetylpyridine azacyclothiosemicarbazone coordinates in a planar conformation to the central Cu atom through the pyridyl N, azomethine N and thiolato S atoms. The interatomic distances are Cu--N = 2.016( 6), Cu--N = 1.963( 5) and Cu--S=2.236(3)~, respectively, with the fourth coordination site occupied by a bromine atom, Cu--Br = 2.359(2) A.

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