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Copper(II) complexes of 6-methyl-2-acetylpyridine N(4)-substituted thiosemicarbazones

โœ Scribed by Douglas X. West; Imporn Thientanavanich; Anthony E. Liberta

Publisher
Springer
Year
1995
Tongue
English
Weight
578 KB
Volume
20
Category
Article
ISSN
0340-4285

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โœฆ Synopsis

Copper(II) complexes of 6-methyl-2-acetylpyridine N(4)substituted thiosemicarbazones, coordinated either as a neutral or a monoanionic ligand, have been prepared and characterized. I.r., electronic and e.p.r, spectra of the complexes, as well as ~H-and ~3C-n.m.r. spectra of the thiosemicarbazones, have been recorded. Both the thiosemicarbazones and their copper(lI) complexes show either modest or no growth inhibitory activity against Aspergillus niger, but the N(4)-dialkyl-and 3-azacycloderivatives, and particularly their copper(II) complexes, have considerable activity against Paecilomyces variotii.

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