Copper(II) complexes of 6-methyl-2-acetylpyridine N(4)substituted thiosemicarbazones, coordinated either as a neutral or a monoanionic ligand, have been prepared and characterized. I.r., electronic and e.p.r, spectra of the complexes, as well as ~H-and ~3C-n.m.r. spectra of the thiosemicarbazones, h
Copper(II) complexes of 6-methyl-2-formylpyridine4N-substituted thiosemicarbazones
โ Scribed by Douglas X. West; Shari L. Dietrich; Imporn Thientanavanich; Christine A. Brown; A. E. Liberta
- Publisher
- Springer
- Year
- 1994
- Tongue
- English
- Weight
- 561 KB
- Volume
- 19
- Category
- Article
- ISSN
- 0340-4285
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โฆ Synopsis
Copper(ll) complexes of 6-methyl-2-formylpyridine thiosemicarbazone, and its *N-methyl-, *N-ethyl-, 4N-phenyl-, 4N-dimethyl-, 4N-diethyl-, 4N-dipropyl-, 3-pyrrolidinyl, 3-piperidinyl-and 3-hexamethyleneiminylthiosemicarbazone derivatives were prepared and characterized. I.r., electronic and e.s.r, spectra of the complexes, as well as ~H and ~ 3C n.m.r, spectra of the thiosemiearbazones, were obtained. The thiosemicarbazones and their eopper(II) complexes show either modest or no growth inhibitory activity against Aspergillus niger, but the *N-dialkyl-and 3-azaeyclo-derivatives exhibit considerable activity against Paecilomyces variotii.
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