Crystal structure of isothiocyanatobis (ethylenediamine) copper(II) bromide [Cu(en)2(NCS)]Br
β Scribed by N. V. Pervukhina; N. V. Podberezskaya; V. N. Kirichenko
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 1982
- Tongue
- English
- Weight
- 413 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0022-4766
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The hydrothermal reactions of CuBr 2 , CuBr, and ethylenediamine have resulted in the synthesis of two new compounds. [Cu(H 2 NCH 2 CH 2 NH 2 ) 2 ] [{Cu 2 Br 4 }] has a two-dimensional sheet structure while [Cu(H 2 NCH 2 CH 2 NH 2 ) 2 ] [{Cu 5 Br 7 }] crystallizes as a three-dimensional network. Bot
An anion (loss of 3N hydrogen) of a 2-acetylpyridine azacyclothiosemicarbazone coordinates in a planar conformation to the central Cu atom through the pyridyl N, azomethine N and thiolato S atoms. The interatomic distances are Cu--N = 2.016( 6), Cu--N = 1.963( 5) and Cu--S=2.236(3)~, respectively, w