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Structure of solanocapsine Synthesis of 3β-acetoxy-22,26-acetylepimino-16α,23-epoxy-5α,22αH,25β H-cholestan-23β-ol

✍ Scribed by M. Nagai; Y. Sato


Book ID
108385023
Publisher
Elsevier Science
Year
1970
Tongue
French
Weight
120 KB
Volume
11
Category
Article
ISSN
0040-4039

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Synthesis of (25S)-5α-cholestane-3β, 26-
✍ Roberto Bovara; Renato Longhi; Francesco Nicotra; Giuseppe Vecchio 📂 Article 📅 1977 🏛 John Wiley and Sons 🌐 French ⚖ 308 KB

## Abstract (25S)–5α‐cholestane‐3β, 26‐diol [2,4,2′,4′–^3^H~4~] was synthesized by hydrogenation of neotigogenin acetate 2, followed by acetylation to (25S)‐5α‐furostane‐3β, 26‐diol diacetate 5; this was oxidized to (25S)–16–22‐dioxo‐5α‐cholestane‐3β, 26‐diol diacetate 6. Clemmensen reduction of th