Structure of mer-(acetonitrile)trichloro[1-methyl-3-(2-pyridyl)-1,2,4-triazole]ruthenium(III)
✍ Scribed by Hage, R. ;Prins, R. ;de Graaff, R. A. G. ;Haasnoot, J. G. ;Reedijk, J. ;Vos, J. G.
- Book ID
- 114504073
- Publisher
- International Union of Crystallography
- Year
- 1988
- Tongue
- English
- Weight
- 306 KB
- Volume
- 44
- Category
- Article
- ISSN
- 0108-2701
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📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.005 A Ê Disorder in main residue R factor = 0.064 wR factor = 0.136 Data-to-parameter ratio = 12.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title compound, C 14 H 12 N 4 , is a disubstituted 1,2,4-triazole derivative. The triazole ring is planar and its dihedral angles with the attached pyridyl and methylphenyl rings are 25.2 (3) and 66.9 (3) , respectively. The crystal structure is stabilized by a number of CÐHÁ Á ÁN hydrogen bonds
The title compound, C 21 H 19 N 5 , has been synthesized and characterized by single-crystal X-ray diffraction. The dihedral angle between the benzene and triazole rings is 123.0 (5) . The triazole ring forms dihedral angles of 36.5 (5) and 50.1 (5) with the two pyridyl rings.