Structure of bis(2,2'-bipyridine)[3,5-bis(2-pyridyl)-1,2,4-triazole]ruthenium(II) hexafluorophosphate hemihydrate
✍ Scribed by Hage, R. ;Turkenburg, J. P. ;de Graaff, R. A. G. ;Haasnoot, J. G. ;Reedijk, J. ;Vos, J. G.
- Book ID
- 114506009
- Publisher
- International Union of Crystallography
- Year
- 1989
- Tongue
- English
- Weight
- 331 KB
- Volume
- 45
- Category
- Article
- ISSN
- 0108-2701
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📜 SIMILAR VOLUMES
Bis[4 0 0 0 -(3,5-dibromophenyl)-2,2 0 0 0 :6 0 0 0 ,2 0 0 00 0 0terpyridine]ruthenium(II) bis(hexafluorophosphate) acetonitrile disolvate
The two pyridine rings in the title compound, C 12 H 10 N 6 , form dihedral angles of 35.7 (2) and 16.8 (2) with the central triazole ring. The molecules exist as centrosymmetrically related dimers and form a three-dimensional network through intermolecular NÐHÁ Á ÁN hydrogen bonds.
In the title compound, [Cu(C 16 H 16 N 4 ) 2 ](ClO 4 ) 2 , the Cu II atom lies on an inversion centre and has a distorted square-planar geometry. In each ligand, the dihedral angle between the triazole and pyridine rings is 9.1 (3) , and that between the triazole and benzene rings is 85.01 ( 14) .