Structure of dichloro({(1R)-[(2S)-2-(diphenylphosphino)-1-ferrocenyl]ethyl}dimethylamine-N,P)palladium(II) deuterochloroform solvate
✍ Scribed by van der Steen, F. H. ;Kanters, J. A.
- Book ID
- 114503810
- Publisher
- International Union of Crystallography
- Year
- 1986
- Tongue
- English
- Weight
- 466 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0108-2701
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📜 SIMILAR VOLUMES
The asymmetric unit of the title compound, [FePd-(C 5 H 5 )(C 11 H 15 NO)Cl(C 18 H 15 P)]ÁCH 2 Cl 2 , contains two molecular palladium complexes and two dichloromethane solvent molecules. The Pd atoms have approximately square planar configurations. Intermolecular O-HÁ Á ÁCl hydrogen bonds stabilize
Single-crystal X-ray study T = 150 K Mean '(C±C) = 0.005 A Ê R factor = 0.031 wR factor = 0.080 Data-to-parameter ratio = 20.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
## Abstract Crystal and solution structures of the [Pd^II^(η^3^‐allyl)] and of the [Pd^II^(η^3^‐1,3‐diphenylallyl)] complexes, 4 and 5, respectively, with (4__S__)‐4‐benzyl‐2‐[2′‐(diphenylphosphino)phenyl]‐4,5‐dihydrooxazole (3) were determined by X‐ray crystallography and 2D‐NMR spectroscopy. Comp