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Structure of dicarbonyl(η5-cyclopentadienyl)[(α,1,2-η)-p-methylbenzyl]tungsten

✍ Scribed by Wadepohl, H. ;Pritzkow, H.


Book ID
114508477
Publisher
International Union of Crystallography
Year
1992
Tongue
English
Weight
332 KB
Volume
48
Category
Article
ISSN
0108-2701

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Reaction of 5 with transition-metal halides affords sandwich and triple-decker complexes. For example, reaction with [((C,Me,)RuCl,},] furnishes the yellow 18e complex 7,14.81 while reaction with [((1,5-cod)RhCI),] leads to formation of the dark-red, 30e triple-decker complex 8 .[4.91