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Variable Electron-Donor Ability of Alkyne Ligands—Synthesis and Structure of Carbonyl(η5-cyclopentadienyl)(η2-1-diethylamino-1-propyne)(η1-p-methylphenylketenyl)tungsten

✍ Scribed by Priv.-Doz. Dr. Fritz R. Kreissl; Dipl.-Chem. Gabriele Reber; Dr. Gerhard Müller

Publisher
John Wiley and Sons
Year
1986
Tongue
English
Weight
245 KB
Volume
25
Category
Article
ISSN
0044-8249

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✦ Synopsis

Reaction of 5 with transition-metal halides affords sandwich and triple-decker complexes. For example, reaction with [((C,Me,)RuCl,},] furnishes the yellow 18e complex 7,14.81 while reaction with [((1,5-cod)RhCI),] leads to formation of the dark-red, 30e triple-decker complex 8 .[4.91

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