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Cycloaddition Reactions of Dicarbonyl(η 5 -cyclopentadienyl)(η 1 -indenyl)iron

✍ Scribed by Kerber, Robert C.; Garcia, Rosa; Nobre, Anthony L.

Book ID
126004836
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
90 KB
Volume
15
Category
Article
ISSN
0276-7333

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Photolytic Reactions of (o-Allylbenzyl)d
Photolytic Reactions of (o-Allylbenzyl)dicarbonyl(η5-cyclopentadienyl)iron
✍ Gebhard Thoma; Bernd Giese 📂 Article 📅 1992 🏛 John Wiley and Sons 🌐 German ⚖ 356 KB

Photolysis of (o-allylbenzyl)dicarbonyl(~5-cyclopentadienyl)iron (4) at 20" in CH,CI, leads to carbon-monoxide loss followed by intramolecular complexation to [~2-(o-allylben~yl)]carhonyl(~5-cyclopentadienyl)iron (13). At 50" in C,D,, a photochemical rearrangement proceeds forming carbonyl (y5-cyclo