Conformational Energy of the (η 5 -Cyclopentadienyl) Iron(II) Dicarbonyl Group
✍ Scribed by Stessman, Nhu Y T.; Ordóñez, Mario; Juaristi, Eusebio; Glass, Richard S.
- Book ID
- 127008674
- Publisher
- American Chemical Society
- Year
- 1998
- Tongue
- English
- Weight
- 80 KB
- Volume
- 63
- Category
- Article
- ISSN
- 0022-3263
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## Abstract Kinetic investigations of the reactions of (prop‐2‐enyl)dicarbonyl(cyclopentadienyl)iron complexes **1** with benzhydrylium ions **3**, and of dicarbonyl(cyclopentadienyl)[(1,2‐__η__)propene]iron(II) tetrafluoroborate (**9**⋅BF~4~) with __π__‐nucleophiles have been performed to elucidat
Photolysis of (o-allylbenzyl)dicarbonyl(~5-cyclopentadienyl)iron (4) at 20" in CH,CI, leads to carbon-monoxide loss followed by intramolecular complexation to [~2-(o-allylben~yl)]carhonyl(~5-cyclopentadienyl)iron (13). At 50" in C,D,, a photochemical rearrangement proceeds forming carbonyl (y5-cyclo