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Structure of carbonyl(2-quinolinecarboxylato-κN,κO)(triphenylphosphite-κP)rhodium(I)

✍ Scribed by Lamprecht, G. J. ;Leipoldt, J. G. ;Roodt, A.

Book ID
114508430
Publisher
International Union of Crystallography
Year
1991
Tongue
English
Weight
332 KB
Volume
47
Category
Article
ISSN
0108-2701

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✍ Brink, Alice ;Roodt, Andreas ;Visser, Hendrik G. 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 700 KB

The title compound, [Rh(C~5~H~7~O~2~)(C~18~H~21~P)(CO)], has the acetylacetonate-chelated Rh^I^ atom in a square-planar geometry. Intramolecular C—H...O hydrogen bonds exist between the acetylacetonate group and the cyclohexyl ring, resulting in a buckling of the acetylacetonate skeleton. Molecules