𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Structure of (3-benzylacetylacetonato-κ2O,O')carbonyl(triphenylphosphine)rhodium(I)

✍ Scribed by Roodt, A. ;Leipoldt, J. G. ;Swarts, J. C. ;Steyn, G. J. J.

Book ID
114508827
Publisher
International Union of Crystallography
Year
1992
Tongue
English
Weight
327 KB
Volume
48
Category
Article
ISSN
0108-2701

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

(Acetylacetonato-κ2O,O′)carbonyl(cyclohe
(Acetylacetonato-κ2O,O′)carbonyl(cyclohexyldiphenylphosphine-κP)rhodium(I)
✍ Brink, Alice ;Roodt, Andreas ;Visser, Hendrik G. 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 700 KB

The title compound, [Rh(C~5~H~7~O~2~)(C~18~H~21~P)(CO)], has the acetylacetonate-chelated Rh^I^ atom in a square-planar geometry. Intramolecular C—H...O hydrogen bonds exist between the acetylacetonate group and the cyclohexyl ring, resulting in a buckling of the acetylacetonate skeleton. Molecules