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Structure of bis(μ-pyridine-2-thione-μ-S)-bis[iodo(pyridine-2-thione-S)copper(I)]

✍ Scribed by Mentzafos, D. ;Terzis, A. ;Karagiannidis, P. ;Aslanidis, P.


Book ID
114505897
Publisher
International Union of Crystallography
Year
1989
Tongue
English
Weight
342 KB
Volume
45
Category
Article
ISSN
0108-2701

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Di-μ-pyridine-2-thiol­ato-bis­[chloro­(t
✍ Marjani, Katayoun ;Davies, Sian C. ;Durrant, Marcus C. ;Hughes, David L. ;Khodam 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 367 KB

The structure of the title compound, [Cu~2~(C~5~H~5~NS)~2~Cl~2~(C~18~H~15~P)~2~], shows two independent molecules, each a dimer bridged through a Cu~2~S~2~ rectangular plane involving the two pyridinethione S atoms and lying about a centre of symmetry. The Cu atoms have a distorted tetrahedral geome