Structure of bis(tetramethylammonium) hexachlororhenate(IV)
✍ Scribed by Loris, R. ;Maes, D. ;Lisgarten, J. N. ;Bettinelli, M. ;Flint, C.
- Book ID
- 114509565
- Publisher
- International Union of Crystallography
- Year
- 1993
- Tongue
- English
- Weight
- 341 KB
- Volume
- 49
- Category
- Article
- ISSN
- 0108-2701
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📜 SIMILAR VOLUMES
The Hf IV atoms in the centrosymmetric title compound, (C 4 H 12 N) 2 ][Hf 2 F 10 (H 2 O) 2 ], are bridged by two F atoms. The Hf IV atoms show pentagonal-bipyramidal coordination. The dianions are linked by water-fluorine hydrogen bonds into layers.
In the title compound, (C 8 H 8 N 4 )[ReCl 6 ]Á2H 2 O, the Re atom occupies an inversion centre and is octahedrally coordinated by chloride anions. The cation also has an inversion centre. Various N-HÁ Á ÁO, O-HÁ Á ÁCl and C-HÁ Á ÁCl interactions help to stabilize the crystal packing.