Structure of bis(pentamethyldiethylenetriamine)disodium hexasulfide
β Scribed by Besser, S. ;Herbst-Irmer, R. ;Stalke, D. ;Brooker, A. T. ;Snaith, R. ;Wright, D. S.
- Book ID
- 114510120
- Publisher
- International Union of Crystallography
- Year
- 1993
- Tongue
- English
- Weight
- 226 KB
- Volume
- 49
- Category
- Article
- ISSN
- 0108-2701
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π SIMILAR VOLUMES
refer to a CC reference length of 1.572 8, based on bond lengths between quaternary C atoms in hydrocarbons, for example 1 ,I,-biadamantyl. This length, however, may not be regarded as a standard value for an unstrained CC single bond, yet is to be viewed as stretched due to nonbonding H . . . H rep
The title compound, [Ni(C 2 H 3 N) 3 (C 9 H 23 N 3 )](PF 6 ) 2 , has the Ni atom in an octahedral environment. It is coordinated by the three N atoms of one chelating 1,1,4,7,7-pentamethyldiethylenetriamine molecule and by three acetonitrile molecules. The charge is balanced by two hexafluoridophosp