Structure of aquachloro[tris(2-aminoethyl)amine]nickel(II) chloride monohydrate
✍ Scribed by Marzotto, A. ;Clemente, D. A. ;Valle, G.
- Book ID
- 114510140
- Publisher
- International Union of Crystallography
- Year
- 1993
- Tongue
- English
- Weight
- 466 KB
- Volume
- 49
- Category
- Article
- ISSN
- 0108-2701
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Yellow crystals of the title compound, [Mn(dien) 2 ][Sb 4 S 7 ]Á-0.5H 2 O (dien = diethylenetriamine = C 4 H 13 N 3 ) were synthesized under solvothermal conditions by reacting MnSb 2 S 4 with pure dien. The Mn 2+ ion is in an octahedral environment of six N atoms of the tridentate dien molecules. T
Acetoacetylferrocene reacted with cobalt chloride and tris(2-aminoethyl)amine in methanol to give the title complex, [CoFe(C~5~H~5~)(C~9~H~8~O~2~)(C~6~H~18~N~4~)](C~24~H~20~B)Cl·C~3~H~6~O, with acetoacetylferrocene and a tripod amine as ligands. The Co atom has slightly distorted octahedral coordina