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Structure of and energy calculations for 1,2,9,10,17,18-hexadehydro[2.2.2]paracyclophane

✍ Scribed by Trueblood, K. ;Mirsky, K. ;Maverick, E. ;Knobler, C. ;Grossenbacher, L.


Book ID
114528751
Publisher
International Union of Crystallography
Year
1982
Weight
894 KB
Volume
38
Category
Article
ISSN
0567-7408

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The 1,9, 17 -triaza[2 2.21 metacyclophane-2, 10, 18-trlone derlvatlves (1) -( 2) have been synthesised X-Ray crystallography shows that the 1,9, 17trimethyl derivative (3) adopts a Crown conformation (11) m the solid state. n m r. spectroscopy lndlcates that both the 1, 9-dlmethyl-17-benzyl- (2) a