A Novel, Non-High-Dilution Method for Preparation of 1,1,2,2,9,9,10,10-Octafluoro[2.2]paracyclophane
β Scribed by Dolbier,, William R.; Duan, Jian-Xin; Roche, Alex J.
- Book ID
- 126973858
- Publisher
- American Chemical Society
- Year
- 2000
- Tongue
- English
- Weight
- 109 KB
- Volume
- 2
- Category
- Article
- ISSN
- 1523-7060
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π SIMILAR VOLUMES
The complete assignment of 19 F, 1 H and 13 C NMR spectra for a monosubstituted octafluoro[2.2]paracyclophane derivative is described for the first time. The unambiguous assignments were achieved through the combination of 19 F-1 H HOESY, 1 H COSY and 19 F COSY techniques and then further confirmed
## Abstract The radical anion of 1,1,2.2,9,9,10, 10βoctafluoro[2.2]paracyclophane (**1**) has been generated by electrolytic reduction of **1** in 1,2βdimethoxyethane (tetrabutylammonium perchlorate as the supporting salt). The hyperfine coupling constants of the eight ^19^Fβnuclei and the eight pr