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Structure of a (μ-Oxo)(dihydroxo)diiron(III) Complex and Its Reactivity toward Phosphodiesters

✍ Scribed by Duboc-Toia, Carole; Ménage, Stéphane; Vincent, Jean-Marc; Averbuch-Pouchot, Marie Thérèse; Fontecave, Marc

Book ID: 127299279
Publisher: American Chemical Society
Year: 1997
Tongue: English
Weight: 125 KB
Volume: 36
Category: Article
ISSN: 0020-1669
DOI: 10.1021/ic9711877

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## Abstract The complex ion [Fe^III^~2~(μ‐O)(phen)~4~(H~2~O)~2~]^4+^ (1) (phen = 1,10‐phenanthroline) and its hydrolytic derivatives [Fe^III^~2~(μ‐O)(phen)~4~(H~2~O)(OH)]^3+^ (1a) and [Fe^III^~2~(μ‐O)(phen)~4~‐ (OH)~2~]^2+^ (2a) coexist in rapid equilibria in the range pH 4.23–5.35 in the presence