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Coordination of gadolinium(iii) ions with a preformed µ-oxo diiron(iii) complex: structural and magnetic data

✍ Scribed by Costes, Jean-Pierre; Dahan, Françoise; Dumestre, Frédéric; Modesto Clemente-Juan, Juan; Garcia-Tojal, Javier; Tuchagues, Jean-Pierre

Book ID
120830238
Publisher
Royal Society of Chemistry
Year
2003
Tongue
English
Weight
196 KB
Volume
3
Category
Article
ISSN
1477-9226

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## Abstract The complex ion [Fe^III^~2~(μ‐O)(phen)~4~(H~2~O)~2~]^4+^ (1) (phen = 1,10‐phenanthroline) and its hydrolytic derivatives [Fe^III^~2~(μ‐O)(phen)~4~(H~2~O)(OH)]^3+^ (1a) and [Fe^III^~2~(μ‐O)(phen)~4~‐ (OH)~2~]^2+^ (2a) coexist in rapid equilibria in the range pH 4.23–5.35 in the presence