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Structure of [1R-(endo,anti)]-3-bromo-1,7-dimethyl-7-vinylbicyclo[2.2.1]heptan-2-one

โœ Scribed by Jauch, J. ;Laderer, H. ;Walz, L.


Book ID
114509086
Publisher
International Union of Crystallography
Year
1992
Tongue
English
Weight
310 KB
Volume
48
Category
Article
ISSN
0108-2701

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(1R,4R)-1-(Hydroxyยญdiphenylยญmethยญyl)-7,7
โœ Gao, Yu-Xing ;Tang, Guo ;Zhao, Yu-Fen ๐Ÿ“‚ Article ๐Ÿ“… 2006 ๐Ÿ› International Union of Crystallography ๐ŸŒ English โš– 157 KB

The title compound, C 22 H 24 O 2 , has been obtained by a Grignard reaction of (1S,4R)-methyl 7,7-dimethyl-2-oxobicyclo[2.2.1]heptane-1-carboxylate with phenylmagnesium bromide. Intramolecular hydrogen bonding is observed between the carbonyl group and the hydroxy group.