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Some Transformations of (-)-(1S,4R)-1-Vinyl-7,7-dimethyl-bicyclo[2.2.1]heptan-2-one

โœ Scribed by N. S. Vostrikov; A. V. Abutkov; M. S. Miftakhov


Book ID
110319812
Publisher
SP MAIK Nauka/Interperiodica
Year
2001
Tongue
English
Weight
69 KB
Volume
37
Category
Article
ISSN
1070-4280

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(1R,4R)-1-(Hydroxyยญdiphenylยญmethยญyl)-7,7
โœ Gao, Yu-Xing ;Tang, Guo ;Zhao, Yu-Fen ๐Ÿ“‚ Article ๐Ÿ“… 2006 ๐Ÿ› International Union of Crystallography ๐ŸŒ English โš– 157 KB

The title compound, C 22 H 24 O 2 , has been obtained by a Grignard reaction of (1S,4R)-methyl 7,7-dimethyl-2-oxobicyclo[2.2.1]heptane-1-carboxylate with phenylmagnesium bromide. Intramolecular hydrogen bonding is observed between the carbonyl group and the hydroxy group.