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(1R,4R)-1-(Hydroxy­diphenyl­meth­yl)-7,7-dimethyl­bicyclo­[2.2.1]heptan-2-one

✍ Scribed by Gao, Yu-Xing ;Tang, Guo ;Zhao, Yu-Fen

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
157 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, C 22 H 24 O 2 , has been obtained by a Grignard reaction of (1S,4R)-methyl 7,7-dimethyl-2-oxobicyclo[2.2.1]heptane-1-carboxylate with phenylmagnesium bromide. Intramolecular hydrogen bonding is observed between the carbonyl group and the hydroxy group.

📜 SIMILAR VOLUMES

1,1′-Ureylenedi-7,7-dimethylbicyclo[2.2.
1,1′-Ureylenedi-7,7-dimethylbicyclo[2.2.1]heptan-2-one
✍ Gao, Yu-Xing ;Liu, Peng ;Fang, Yi-Xin ;Tang, Guo ;Zhao, Yu-Fen 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 774 KB

The title compound, C 19 H 28 N 2 O 3 , was obtained by the acidic hydrolysis of (1S,4R)-1-isocyanato-7,7-dimethylbicyclo[2.2.1]heptan-2-one followed by addition of aqueous sodium hydroxide. N-HÁ Á ÁO hydrogen bonds link the molecules into chains running along the a axis.