Structure of 1-methyl-3-(2-methyl-2-nitrovinyl)indole
✍ Scribed by Fonseca, I. ;Martínez-Carrera, S. ;García-Blanco, S. ;Rodríguez, J. G.
- Book ID
- 114504651
- Publisher
- International Union of Crystallography
- Year
- 1987
- Tongue
- English
- Weight
- 323 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0108-2701
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📜 SIMILAR VOLUMES
In the title molecule, C 17 H 14 N 2 O 2 , the indole ring system is essentially planar and makes a dihedral angle of 87.93 (3) with the plane of the benzene ring. The nitrovinyl double bond adopts the E geometry.
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A simple and efficient synthesis of novel 2-heteroaryl-substituted 1H-indole-2-carboxylates and gcarbolines, compounds 1 -3, from methyl 2-(2-methoxy-2-oxoethyl)-1-methyl-1H-indole-3-carboxylate (4) by the enaminone methodology is presented.