𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Structure features of ions and ion pairs of nitroarene anionic σ-complexes in aprotic solvents

✍ Scribed by E.N Alifanova; K.K Kalninsh; A.Ja Kaminsky; Yu.M Atroshchenko; S.S Gitis; A.D Kutzenko; P.V Chudakov; E.Yu Tarasova

Publisher
Elsevier Science
Year
2001
Tongue
English
Weight
457 KB
Volume
91
Category
Article
ISSN
0167-7322

No coin nor oath required. For personal study only.

✦ Synopsis

The structure of ions and ion pairs of Meisenheimer and Janovsky o-complexes of 1,3,5trinitrobenzene has been studied by derivative spectroscopy and semiempitical quantum chemical PM3 and CNDO/S methods. On the base of comparison of theoretical and experimental electronic absorption spectra the three types of co-ordination of anion and cation have been defined. It was established that the structure of ion pairs is determined by the nature of the subsituents of the pyramidal unit.

📜 SIMILAR VOLUMES

The influence of polar solvents on ions
The influence of polar solvents on ions and ion pairs in the anionic polymerization of styrene
✍ B.J. Schmitt; G.V. Schulz 📂 Article 📅 1975 🏛 Elsevier Science 🌐 English ⚖ 885 KB

In the rather polar organic solvents dimethoxyethane, tetrahydrofuran and 3-methyltetrahydrofuran, the behaviour of contact ion pairs, solvent-separated ion pairs and free carbanions of polystyryl sodium has been investigated by kinetic and conductivity measurements• Both the equilibrium between the

IR study of solutions of lithium trifluo
IR study of solutions of lithium trifluoroacetate in non-aqueous solvents. Structure of ion pairs and triple ions
✍ A. Regis; J. Corset 📂 Article 📅 1975 🏛 Elsevier Science 🌐 English ⚖ 476 KB

Analysis of.internalvibrations of the ~JCO~ anion of the lithium trifluoroacekkdissolved in acetonitrile or dimethyl-.,' .' sulphoede shows 5yu-in' cty ofss&&tion~. In dimethylsulphoxide solutions, an e,quilibrium is .obxrve between frqc ions ,, and ion ptis; in aeeto$ile even at relat&ely low con