## Abstract ^7^Li and ^13^C solid‐state magic angle spinning NMR spectra were measured for three benzyllithium systems, α‐(phenylthio)benzyllithium, α‐phenyl‐α‐lithiodithiane and α‐(trimethylsilyl)benzyllithium, stabilized by different ligands (THF, PMDTA, TMEDA, [12]crown‐4). They were analyzed wi
✦ LIBER ✦
Identification and Mechanistic Consequences of Contact and Solvent-Separated Ion Pair Structures in Organolithium Chemistry
✍ Scribed by H. J. Reich; A. W. Sanders; M. J. Bevan; W. H. Sikorski; R. R. Dykstra
- Publisher
- John Wiley and Sons
- Year
- 2003
- Weight
- 52 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0931-7597
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The solvent effect on the emission and absorption properties of the ~-naphthoIate anion was studied and the lifetimes measured. In all solvents only a single peah is observed in the spectra. In spite of the lack of resolved spectral bands, the combination of shifts and lifetimes made it possible to