IR study of solutions of lithium trifluoroacetate in non-aqueous solvents. Structure of ion pairs and triple ions

✍ Scribed by A. Regis; J. Corset

• Publisher: Elsevier Science
• Year: 1975
• Tongue: English
• Weight: 476 KB
• Volume: 32
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(75)85215-8

✦ Synopsis

Analysis of.internalvibrations of the ~JCO~ anion of the lithium trifluoroacekkdissolved in acetonitrile or dimethyl-.,'

.' sulphoede shows 5yu-in' cty ofss&&tion~.

In dimethylsulphoxide solutions, an e,quilibrium is .obxrve between frqc ions ,, and ion ptis; in aeeto$ile even at relat&ely low concentrati&s (low3 M) rriple anion and aggregates are present, togeth-