## Abstract Two new bidesmoside triterpenoid saponins were isolated from stems of __Cordia piauhiensis__. Their structures, characterized as 3‐__O__‐α‐L‐rhamnopyranosyl‐(1 → 2)‐β‐D‐glucopyranosyl pomolic acid 28‐__O__‐β‐D‐glucopyranosyl ester (1) and 3‐__O__‐α‐L‐rhamnopyranosyl‐(1 → 2)‐β‐D‐glucopyr
Structure elucidation and total assignment of 1H and 13C NMR data for a new bisdesmoside saponin from Cordia piauhiensis
✍ Scribed by Renata P. Santos; Francisco A. Viana; Telma Leda G. Lemos; Edilberto R. Silveira; Raimundo Braz-Filho; Otília Deusdênia L. Pessoa
- Publisher
- John Wiley and Sons
- Year
- 2003
- Tongue
- English
- Weight
- 104 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0749-1581
- DOI
- 10.1002/mrc.1241
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✦ Synopsis
Abstract
Extensive 1D (^1^H NMR, HBBD‐^13^C NMR, DEPT‐^13^C NMR) and 2D (COSY, TOCSY, NOESY, HMQC and HMBC) NMR analysis was used to characterize the structure of a new bisdesmoside saponin isolated from the methanol extract of stems of Cordia piauhiensis Fresen as 3β‐O‐[α‐L‐rhamnopyranosyl‐(1 → 2)‐β‐D‐glucopyranosyl]ursolic acid 28‐O‐[β‐D‐glucopyranosyl‐(1 → 6)‐β‐D‐glucopyranosyl] ester. Copyright © 2003 John Wiley & Sons, Ltd.
📜 SIMILAR VOLUMES
A careful NMR analysis with full assignment of the 1 H and 13 C spectral data for two minor saponins isolated from stems of Cordia piauhiensis is reported. These saponins were isolated by high-performance liquid chromatography and characterized as 3b-O-[a-L-rhamnopyranosyl-.1 → 2/-b-D-glucopyranosyl
## Abstract From the roots of __Cordia leucocephala__ (Boraginaceae), two new meroterpenoid naphthoquinones, 6‐[10‐(12,12‐dimethyl‐13α‐hydroxy‐16‐methenyl‐cyclohexyl)ethyl]‐1,4‐naphthalenedione (cordiaquinone L) and 5‐methyl‐6‐[10‐(12,12‐dimethyl‐13β‐hydroxy‐16‐methenyl‐cyclohexyl)methyl‐1,4‐naphth
## Abstract Conventional 1D NMR methods and 2D shift‐correlated NMR experiments (COSY, HMQC, HMBC) were used for the structural elucidation and ^1^H and ^13^C chemical shifts assignments of four new types of chalcone dimers isolated from __Myracrodruon urundeuva__. Copyright © 2003 John Wiley & Son
## Abstract Two novel unsaturated E‐ring pentacyclic triterpenoid saponins, ilexhainanoside A and ilexhainanoside B, were isolated from the leaves of __Ilex hainanensis__. Their chemical structures were determined by MS, NMR spectroscopy and chemical analysis. Complete assignments of the ^1^H and ^
## Abstract Ilexpernoside A and ilexpernoside B, two new pentacyclic C~4~‐nortriterpenoid saponins, were isolated from the leaves of __Ilex pernyi__ Franch. Their chemical structures were determined by MS, NMR spectroscopy and chemical analysis. Complete assignments of the ^1^H and ^13^C NMR spectr