𝔖 Bobbio Scriptorium
✦   LIBER   ✦

1H and 13C NMR assignments for two new cordiaquinones from roots of Cordia leucocephala

✍ Scribed by Jaécio Carlos Diniz; Francisco Arnaldo Viana; Odaci Fernandes Oliveira; Maria Aparecida M. Maciel; Maria da Conceição de Menezes Torres; Raimundo Braz-Filho; Edilberto R. Silveira; Otília Deusdênia L. Pessoa


Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
117 KB
Volume
47
Category
Article
ISSN
0749-1581

No coin nor oath required. For personal study only.

✦ Synopsis


Abstract

From the roots of Cordia leucocephala (Boraginaceae), two new meroterpenoid naphthoquinones, 6‐[10‐(12,12‐dimethyl‐13α‐hydroxy‐16‐methenyl‐cyclohexyl)ethyl]‐1,4‐naphthalenedione (cordiaquinone L) and 5‐methyl‐6‐[10‐(12,12‐dimethyl‐13β‐hydroxy‐16‐methenyl‐cyclohexyl)methyl‐1,4‐naphthalenedione (cordiaquinone M) were isolated. Their structures were elucidated after detailed 1D and 2D NMR (COSY, HSQC, HMBC and NOESY) data analyses and comparison with literature data for analogous compounds. Copyright © 2008 John Wiley & Sons, Ltd.


📜 SIMILAR VOLUMES


Complete 1H and 13C NMR assignments of t
✍ Kun Wei; Wei Li; Kazuo Koike; Yuping Pei; Yingjie Chen; Tamotsu Nikaido 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 155 KB 👁 1 views

## Abstract Using modern NMR techniques, including DQF‐COSY, NOESY, HETCOR and HMBC, the full assignments of all ^1^H and ^13^C chemical shifts were made for stigmastane‐3,6‐dione and stigmast‐4‐ene‐3,6‐dione, isolated from the roots of __Piper nigrum__ (Piperaceae). Their stereochemistry was resol

1H and 13C NMR spectral data of new sapo
✍ Renata P. Santos; Edilberto R. Silveira; Daniel Esdras de A. Uchôa; Otília Deusd 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 126 KB 👁 1 views

## Abstract Two new bidesmoside triterpenoid saponins were isolated from stems of __Cordia piauhiensis__. Their structures, characterized as 3‐__O__‐α‐L‐rhamnopyranosyl‐(1 → 2)‐β‐D‐glucopyranosyl pomolic acid 28‐__O__‐β‐D‐glucopyranosyl ester (1) and 3‐__O__‐α‐L‐rhamnopyranosyl‐(1 → 2)‐β‐D‐glucopyr

Structure elucidation and total assignme
✍ Renata P. Santos; Francisco A. Viana; Telma Leda G. Lemos; Edilberto R. Silveira 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 104 KB 👁 1 views

## Abstract Extensive 1D (^1^H NMR, HBBD‐^13^C NMR, DEPT‐^13^C NMR) and 2D (COSY, TOCSY, NOESY, HMQC and HMBC) NMR analysis was used to characterize the structure of a new bisdesmoside saponin isolated from the methanol extract of stems of __Cordia piauhiensis__ Fresen as 3β‐__O__‐[α‐L‐rhamnopyrano

Complete 13C and 1H NMR spectral assignm
✍ C. Narayanan Manoj; R. Priya Rao; M. Gopalakrishnan Sethuraman; N. Shanmugam Nag 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 79 KB 👁 1 views

## Abstract Two methoxylated isoflavones were isolated form the roots of __Dalbergia horrida__. These compounds show great promise as pharmaceutical agents. The ^1^H and ^13^C NMR spectra of the compounds were completely assigned by using a combination of 2D NMR experiments which included ^1^H–^1^H

1H and 13C NMR assignments for two new a
✍ Haitao Chang; Yoshihito Okada; Toru Okuyama; Pengfei Tu 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 136 KB 👁 1 views

## Abstract Two novel angular‐type furanocoumarin glycosides, peucedanoside A (1) and peucedanoside B (2), along with a known compound apterin (3), were isolated from the roots of __Peucedanum praeruptorum__ Dunn. Their chemical structures were determined by MS, NMR spectroscopy and chemical analys

1H and 13C NMR assignments for two new s
✍ Hua-Wei Geng; Xiao-Jian Liao; Shi-Hai Xu 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 87 KB 👁 1 views

## Abstract Two new steroids isolated from EtOH extracts of the South China Sea soft coral __Chromonephthea__ sp. were identified. One‐dimensional (1D) and two‐dimensional (2D) NMR experiments including COSY, HSQC, HMBC and NOESY were used for the determination of their structure. Copyright © 2008