## Abstract Using modern NMR techniques, including DQF‐COSY, NOESY, HETCOR and HMBC, the full assignments of all ^1^H and ^13^C chemical shifts were made for stigmastane‐3,6‐dione and stigmast‐4‐ene‐3,6‐dione, isolated from the roots of __Piper nigrum__ (Piperaceae). Their stereochemistry was resol
1H and 13C NMR assignments for two new cordiaquinones from roots of Cordia leucocephala
✍ Scribed by Jaécio Carlos Diniz; Francisco Arnaldo Viana; Odaci Fernandes Oliveira; Maria Aparecida M. Maciel; Maria da Conceição de Menezes Torres; Raimundo Braz-Filho; Edilberto R. Silveira; Otília Deusdênia L. Pessoa
- Publisher
- John Wiley and Sons
- Year
- 2009
- Tongue
- English
- Weight
- 117 KB
- Volume
- 47
- Category
- Article
- ISSN
- 0749-1581
- DOI
- 10.1002/mrc.2373
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✦ Synopsis
Abstract
From the roots of Cordia leucocephala (Boraginaceae), two new meroterpenoid naphthoquinones, 6‐[10‐(12,12‐dimethyl‐13α‐hydroxy‐16‐methenyl‐cyclohexyl)ethyl]‐1,4‐naphthalenedione (cordiaquinone L) and 5‐methyl‐6‐[10‐(12,12‐dimethyl‐13β‐hydroxy‐16‐methenyl‐cyclohexyl)methyl‐1,4‐naphthalenedione (cordiaquinone M) were isolated. Their structures were elucidated after detailed 1D and 2D NMR (COSY, HSQC, HMBC and NOESY) data analyses and comparison with literature data for analogous compounds. Copyright © 2008 John Wiley & Sons, Ltd.
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