## Abstract Extensive 1D (^1^H NMR, HBBD‐^13^C NMR, DEPT‐^13^C NMR) and 2D (COSY, TOCSY, NOESY, HMQC and HMBC) NMR analysis was used to characterize the structure of a new bisdesmoside saponin isolated from the methanol extract of stems of __Cordia piauhiensis__ Fresen as 3β‐__O__‐[α‐L‐rhamnopyrano
1H and 13C NMR spectral data of new saponins from Cordia piauhiensis
✍ Scribed by Renata P. Santos; Edilberto R. Silveira; Daniel Esdras de A. Uchôa; Otília Deusdênia L. Pessoa; Francisco Arnaldo Viana; Raimundo Braz-Filho
- Publisher
- John Wiley and Sons
- Year
- 2007
- Tongue
- English
- Weight
- 126 KB
- Volume
- 45
- Category
- Article
- ISSN
- 0749-1581
- DOI
- 10.1002/mrc.2026
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✦ Synopsis
Abstract
Two new bidesmoside triterpenoid saponins were isolated from stems of Cordia piauhiensis. Their structures, characterized as 3‐O‐α‐L‐rhamnopyranosyl‐(1 → 2)‐β‐D‐glucopyranosyl pomolic acid 28‐O‐β‐D‐glucopyranosyl ester (1) and 3‐O‐α‐L‐rhamnopyranosyl‐(1 → 2)‐β‐D‐glucopyranosyl oleanolic acid 28‐O‐β‐D‐glucopyranosyl‐(1 → 6)‐β‐D‐glucopyranosyl ester (2), were unequivocally established after extensive NMR (^1^H, ^13^C, DEPT 135 , COSY, HSQC, HMBC, TOCSY, and NOESY) studies. Copyright © 2007 John Wiley & Sons, Ltd.
📜 SIMILAR VOLUMES
A careful NMR analysis with full assignment of the 1 H and 13 C spectral data for two minor saponins isolated from stems of Cordia piauhiensis is reported. These saponins were isolated by high-performance liquid chromatography and characterized as 3b-O-[a-L-rhamnopyranosyl-.1 → 2/-b-D-glucopyranosyl
## Abstract Three new oleanane‐type triterpenoid saponins, ilexhainanoside C, D and E, all with 24, 28‐dioic acid groups, were isolated from the leaves of __Ilex hainanensis__. They were 3β‐hydroxyolean‐12‐ene‐24, 28‐dioic acid‐28‐__O__‐β‐D‐glucopyranoside(**1**), 3β, 19α‐dihydroxyolean‐12‐ene‐24,
## Abstract From the roots of __Cordia leucocephala__ (Boraginaceae), two new meroterpenoid naphthoquinones, 6‐[10‐(12,12‐dimethyl‐13α‐hydroxy‐16‐methenyl‐cyclohexyl)ethyl]‐1,4‐naphthalenedione (cordiaquinone L) and 5‐methyl‐6‐[10‐(12,12‐dimethyl‐13β‐hydroxy‐16‐methenyl‐cyclohexyl)methyl‐1,4‐naphth
## Abstract Two novel unsaturated E‐ring pentacyclic triterpenoid saponins, ilexhainanoside A and ilexhainanoside B, were isolated from the leaves of __Ilex hainanensis__. Their chemical structures were determined by MS, NMR spectroscopy and chemical analysis. Complete assignments of the ^1^H and ^
## Abstract Ilexpernoside A and ilexpernoside B, two new pentacyclic C~4~‐nortriterpenoid saponins, were isolated from the leaves of __Ilex pernyi__ Franch. Their chemical structures were determined by MS, NMR spectroscopy and chemical analysis. Complete assignments of the ^1^H and ^13^C NMR spectr