Tl-2201 superconductor is discovered by high-resolution time-of-flight neutron and synchrotron X-ray powder diffraction studies of "orthorhombic Tl-2201". Oxygen-rich compositions with Tc values up to 50 K are monoclinic whereas less oxidized samples with Tc values of 50-90 K are orthorhombic (Fmmm)
Structure and superconducting properties of Bi2Ba2−xMxCuO6+δ
✍ Scribed by T.N. Kol'tsova; G.D. Nipan; N.F. Vedernikov; E.A. Tishchenko; Yu.F. Orekhov
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- English
- Weight
- 76 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0749-6036
No coin nor oath required. For personal study only.
✦ Synopsis
The effect of oxygen nonstoichiometry and barium cation substitution on the structure and superconducting properties of Bi 2 Ba 2-x M x CuO 6+δ (M = Sr, Ru, Rh, Pd, In, Sb or Pb; x changed from 0 to 0.2) were studied. The cation-substituted samples annealed in oxygen flow contain a superconducting phase with T init c near 95 K.
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The low-temperature fluorination of a range of insulating alkaline earth cuprates Sr 2 -x A x CuO 3 (A ؍ Ca (04x42); A ؍ Ba (04x40.6)) can result in superconducting oxide fluorides Sr 2 -x A x CuO 2 F 2; . In contrast, conventional high-temperature solid-state reactions produce thermodynamically
Structure and Physicochemical Properties of Y 2 Ba 1-x MxCuO 5 (M: Sr, Ca) Solid Solutions. -Crystal structure, thermal expansion, and electric conductivity of the title solid solutions Y 2 Ba 1-x MxCuO 5 (0≤x≤1) are studied in the temperature interval 293-1073 K. Solid solutions with M: Sr and M: