The iminophosphane, ~Bu~P-P=N-NR~ (R=SiMeJ, produced by base-catalyzed elimination of ClSiMe3 from the corresponding phosphane, possesses an unusually long PN bond (162 pm), which is in accord with quantum chemical calculations.
✦ LIBER ✦
Structure and bonding in crystals, Vol. 1
✍ Scribed by G. Kühn; Michael O'Keeffe; Alexandra Navrotsky; G. Kühn
- Publisher
- John Wiley and Sons
- Year
- 1982
- Tongue
- English
- Weight
- 87 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0232-1300
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
1-Phosphinodiazaphosphene: Synthesis, cr
✍
Oliver Altmeyer; Edgar Niecke; Martin Nieger; Thilo Busch; Wolfgang W. Schoeller
📂
Article
📅
1990
🏛
John Wiley and Sons
🌐
English
⚖ 291 KB
Book Review: Structure and Bonding in Cr
✍
Hans-Jörg Deiseroth
📂
Article
📅
1982
🏛
John Wiley and Sons
🌐
English
⚖ 261 KB
👁 2 views
Diaminodiphosphenes—Synthesis, Crystal S
✍
Prof. Dr. Edgar Niecke; Dr. Reinhold Rüger; Manfred Lysek; Priv.-Doz. Dr. Siegfr
📂
Article
📅
1983
🏛
John Wiley and Sons
🌐
English
⚖ 354 KB
👁 1 views
Diaminodiphosphenes – Synthesis, Crystal
✍
Prof. Dr. Edgar Niecke; Dr. Reinhold Rüger; Manfred Lysek; Dr. Siegfried Pohl; P
📂
Article
📅
1983
🏛
John Wiley and Sons
🌐
English
⚖ 315 KB
👁 1 views
Anionic Polymeric Bonds in Nickel Ditell
✍
W. Bensch; W. Heid; M. Muhler; S. Jobic; R. Brec; J. Rouxel
📂
Article
📅
1996
🏛
Elsevier Science
🌐
English
⚖ 316 KB
Hydrogen bonds and local symmetry in the
✍
Anastasia Vyalikh; Konrad Zesewitz; Ulrich Scheler
📂
Article
📅
2010
🏛
John Wiley and Sons
🌐
English
⚖ 211 KB
## Abstract First‐principles quantum mechanical calculations of NMR chemical shifts and quadrupolar parameters have been carried out to assign the ^27^Al MAS NMR resonances in gibbsite. The ^27^Al NMR spectrum shows two signals for octahedral aluminum revealing two aluminum sites coordinated by six