Diaminodiphosphenes—Synthesis, Crystal Structure and Bonding Properties
✍ Scribed by Prof. Dr. Edgar Niecke; Dr. Reinhold Rüger; Manfred Lysek; Priv.-Doz. Dr. Siegfried Pohl; Prof. Dr. Wolfgang Schoeller
- Publisher
- John Wiley and Sons
- Year
- 1983
- Tongue
- English
- Weight
- 354 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
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Single crystals of (Ca 3 N)Tl (Pm 3 m, No. 221, a = 4.9851(3) A Ê ; Z = 1) with a metallic luster and black single phase powders of the ternary nitride were obtained from reactions of the respective metals with nitrogen at maximum temperatures of 950 °C. (Ca 3 N)Tl crystallizes in an antiperovskite-
1141 important Ag Ag distances in 3 [pm] ( 2 0 . 4 pm): Agl -Ag2 320.0. Agl -Ag3 294.3. Agl -AglO 294.3. Ag2 ~A g 3 280.0, Ag2-Ag7 280.6. Ag2-Ag8 311.2. Ag3 Ag4 7X7.4, Ag3-Ag12 291 5, Ag4-AgS 287.1, Ag4-Ag12 298.3. Ag4 Ag15 293.5. Ag5 Ag6 287.7. Ag5-Ag7 276.9. Ag5-Ag15 273.6, Ag6-Ag7 312.3. Ag6 -Ag1