1-Phosphinodiazaphosphene: Synthesis, crystal structure, and bonding properties

✍ Scribed by Oliver Altmeyer; Edgar Niecke; Martin Nieger; Thilo Busch; Wolfgang W. Schoeller; Dietmar Stalke

• Publisher: John Wiley and Sons
• Year: 1990
• Tongue: English
• Weight: 291 KB
• Volume: 1
• Category: Article
• ISSN: 1042-7163
• DOI: 10.1002/hc.520010212

✦ Synopsis

The iminophosphane, ~Bu~P-P=N-NR~ (R=SiMeJ, produced by base-catalyzed elimination of ClSiMe3 from the corresponding phosphane, possesses an unusually long PN bond (162 pm), which is in accord with quantum chemical calculations.