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Structural Studies on the Radical Cations of Benzene, Naphthalene, Biphenylene, and Anthracene Fully Annelated with Bicyclo[2.2.2]octene Frameworks

โœ Scribed by Matsuura, Akira; Nishinaga, Tohru; Komatsu, Koichi

Book ID
126160047
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
138 KB
Volume
122
Category
Article
ISSN
0002-7863

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๐Ÿ“œ SIMILAR VOLUMES

Synthesis, structure and properties of n
Synthesis, structure and properties of naphthalene fully annelated with bicyclo[2.2.2]octene frameworks
โœ Akira Matsuura; Tohru Nishinaga; Koichi Komatsu ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 230 KB

Novel naphthalene derivative 4 annelated with four bicyclo[2.2.2]octene frameworks was synthesized. X-ray analysis showed that the acene core of 4 deviates from planarity. The remarkable effect of annelation was observed in its oxidizability as revealed by cyclic voltammetry, and 4 was readily conve

Synthesis and electronic properties of a
Synthesis and electronic properties of anthracene fully annelated with bicyclo[2.2.2]octene frameworks
โœ Akira Matsuura; Tohru Nishinaga; Koichi Komatsu ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 213 KB

Anthracene derivative 4 annelated with four bieycio[2.2.2]octeae (BCO) units was newly synthesized by the Diels--Alder reaction of BCO dimer withp-benzoquinone as a key reaction, and its electronic properties w~'e investigated. The remarkable effect of BCO annelation wasobserved in its redox belmvio