Phenylselenolato Complexes of Cyclopenta
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Max Herberhold; Melanie Keller; Walter Kremnitz; Thomas Daniel; Wolfgang Milius;
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Article
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1998
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John Wiley and Sons
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German
β 132 KB
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Diphenyl diselenide reacts with [CpRh(CO) 2 ] (1) to give the dimer [CpRh(SePh)(l-SePh)] 2 (2), the solid state structure of which has been determined by X-ray analysis; the dimeric structure is retained in solution. In contrast, [Cp\*Rh(CO) 2 ] (4) gives the ionic product [Cp\*Rh(l-SePh) 3 RhCp\*][