Diphenyl diselenide reacts with [CpRh(CO) 2 ] (1) to give the dimer [CpRh(SePh)(l-SePh)] 2 (2), the solid state structure of which has been determined by X-ray analysis; the dimeric structure is retained in solution. In contrast, [Cp\*Rh(CO) 2 ] (4) gives the ionic product [Cp\*Rh(l-SePh) 3 RhCp\*][
Structural, Spectroscopic, and Chemical Properties of the First Low-Spin Iron(III) Semiquinonate Complexes in the Solid State and in Solution
✍ Scribed by Welf O. Koch; Volker Schünemann; Michael Gerdan; Alfred X. Trautwein; Hans-Jörg Krüger
- Publisher
- John Wiley and Sons
- Year
- 1998
- Tongue
- English
- Weight
- 243 KB
- Volume
- 4
- Category
- Article
- ISSN
- 0947-6539
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