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Structural Consequences of the Prohibition of Hydrogen Bonding in Copper−Guanidine Systems

✍ Scribed by Oakley, Sarah H.; Coles, Martyn P.; Hitchcock, Peter B.

Book ID
125966788
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
97 KB
Volume
43
Category
Article
ISSN
0020-1669

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The structural role of a sidechain to side-chain protein hydrogen bond is examined using trans-substitution of the proximal histidine of myoglobin with methylimidazoles (Barrick, Biochemistry 1994;33:6546 -6554). Modification of the chemical structure of exogenous ligands allows this hydrogen bond t