Structural and energetic consequences of the formation of intramolecular hydrogen bonds
โ Scribed by A. Koll; A. Karpfen; P. Wolschann
- Publisher
- Elsevier Science
- Year
- 2006
- Tongue
- English
- Weight
- 289 KB
- Volume
- 790
- Category
- Article
- ISSN
- 0022-2860
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Measurements were made in CCI, of the formation constant K,, of the 1 : l hydrogen-bonded complexes between the reference donor 4-fluorophenol and the intramolecular hydrogen-bonded systems I (one lone pair on heteroatom Y, one intramolecular hydrogen bond: 8-hydroxyquinaldine and 2-(2-hydroxyphenyl
The structural role of a sidechain to side-chain protein hydrogen bond is examined using trans-substitution of the proximal histidine of myoglobin with methylimidazoles (Barrick, Biochemistry 1994;33:6546 -6554). Modification of the chemical structure of exogenous ligands allows this hydrogen bond t