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Structural Chemistry of Chiral BINAP .eta.3-Allyl Complexes of Pd(II). Multinuclear NMR and X-ray Diffraction Studies on Exo-Methylene Cyclopentene and .beta.-Pinene Allyl Complexes

✍ Scribed by Pregosin, Paul S.; Rueegger, Heinz; Salzmann, Renzo; Albinati, Alberto; Lianza, Francesca; Kunz, Roland W.


Book ID
127390156
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
906 KB
Volume
13
Category
Article
ISSN
0276-7333

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Structural studies on chiral (π-Allyl)Pd
✍ Paul S. Pregosin; Renzo Salzmann 📂 Article 📅 1994 🏛 John Wiley and Sons 🌐 English ⚖ 426 KB

## Abstract The chiral (π‐allyl)Pd(II) complex [Pd(η^3^CH~3~CHCHCH~2~)(__S, S__‐Chiraphos)]CF~3~SO~3~ was shown to exist in four isomeric forms (two diastereomeric and two geometric). Aspects of their three‐dimensional structures were elucidated using ^1^H, ^13^C and ^31^P one‐ and two‐dimensional