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Chemistry of PdII complexes containing both BINAP (2′2′-bis(diphenylphosphino)binaphthyl) and a η3-pinene or -allyl ligand. NMR studies on [Pd(η3-C10H15){S(−)BINAP}] (CF3SO3). The crystal structure of [Pd(η3-C10H15)(4,4′-dimethylbipyridine)](CF3SO3)

✍ Scribed by Christian J. Ammann; Paul S. Pregosin; Heinz Rüegger; Alberto Albinati; Francesca Lianza; Roland W. Kunz

Publisher: Elsevier Science
Year: 1992
Tongue: English
Weight: 1009 KB
Volume: 423
Category: Article
ISSN: 0022-328X
DOI: 10.1016/0022-328x(92)83135-5

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Structural studies on chiral (π-Allyl)Pd

Structural studies on chiral (π-Allyl)Pd(II) complexes. 1H, 13C and 31P NMR Studies of [Pd(η3-CH3CHCHCH2)(S, S-Chiraphos)] CF3SO3

✍ Paul S. Pregosin; Renzo Salzmann 📂 Article 📅 1994 🏛 John Wiley and Sons 🌐 English ⚖ 426 KB

## Abstract The chiral (π‐allyl)Pd(II) complex [Pd(η^3^CH~3~CHCHCH~2~)(__S, S__‐Chiraphos)]CF~3~SO~3~ was shown to exist in four isomeric forms (two diastereomeric and two geometric). Aspects of their three‐dimensional structures were elucidated using ^1^H, ^13^C and ^31^P one‐ and two‐dimensional