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Structural and Magnetic Investigations of the Mixed-Valence FeII,III Two-Dimensional Layer Complex, [Fe2IIFe2III(HCOO)10(C6H7N)6]n

✍ Scribed by Jacob Overgaard; Eva Rentschler; Grigore A. Timco; Finn K. Larsen


Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
372 KB
Volume
5
Category
Article
ISSN
1439-4235

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The novel thioantimonate(III) [Fe(C 4 H 13 N 3 ) 2 ]Sb 6 S 10 β€’ 0.5 H 2 O was synthesised under mild hydrothermal conditions by allowing elemental Fe, Sb, and S to react in a 50% diethylenetriamine (dien) solution. The compound crystallises in the monoclinic space group C2/c with a = 33.789(3), b =